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Free, publicly-accessible full text available November 18, 2025
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Stiles, Joseph W; Hoff, Brianna; Curria, Maria C; Lee, Scott B; Yuan, Fang; Cheng, Guangming; Katmer, Fatmagül; Skorupskii, Grigorii; Xie, Jiaze; Leeman, Josh; et al (, Chemistry of Materials)
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Villalpando, Graciela; Jovanovic, Milena; Hoff, Brianna; Jiang, Yi; Singha, Ratnadwip; Yuan, Fang; Hu, Haoyu; Călugăru, Dumitru; Mathur, Nitish; Khoury, Jason F; et al (, Science Advances)Flat bands that do not merely arise from weak interactions can produce exotic physical properties, such as superconductivity or correlated many-body effects. The quantum metric can differentiate whether flat bands will result in correlated physics or are merely dangling bonds. A potential avenue for achieving correlated flat bands involves leveraging geometrical constraints within specific lattice structures, such as the kagome lattice; however, materials are often more complex. In these cases, quantum geometry becomes a powerful indicator of the nature of bands with small dispersions. We present a simple, soft-chemical processing route to access a flat band with an extended quantum metric below the Fermi level. By oxidizing Ni-kagome material Cs2Ni3S4to CsNi3S4, we see a two orders of magnitude drop in the room temperature resistance. However, CsNi3S4is still insulating, with no evidence of a phase transition. Using experimental data, density functional theory calculations, and symmetry analysis, our results suggest the emergence of a correlated insulating state of unknown origin.more » « less
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Song, Xiaoyu; Hoff, Brianna; Singha, Ratnadwip; Stiles, Joseph W; Skorupskii, Grigorii; Khoury, Jason F; Cheng, Guangming; Kamm, Franziska; Uzan, Ayelet J; Dulovic, Stephanie; et al (, Chemistry of Materials)
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